Remark 4
Tag 0AV0, permanent. Cite it as [Bourbaki, Tag 0AV0].
Lie Groups and Lie Algebras, chapter VI, § 1. Root systems
Assertion (vi) of Th. 2 shows that the map is a bijection from the set of chambers to the set of bases. Consequently, acts simply-transitively on the set of bases.
Bourbaki puts the proof directly after the statement, so what is above is the statement and its proof together.