Proposition 7
Tag 06S1, permanent. Cite it as [Bourbaki, Tag 06S1].
Algebra, V, p. 109, § 14. Transcendental extensions
Let E be an extension of a field K. Every transcendence basis of E is a maximal element of the set (ordered by inclusion) of subsets of E algebraically free over K. Conversely, if S is a subset of E such that E is algebraic over , every maximal algebraically free subset of S is a transcendence basis of E.
Let B be a transcendence basis of E over K and . Then is algebraic over ; by V, p. 107, Prop. 4, the subset of E is not algebraically free over K, whence the first part of the proposition. Secondly, if E is algebraic over and B is a maximal algebraically free part of S, it follows from the Cor. of Prop. 4 that every is algebraic over ; hence (V, p. 18, Cor. 1) is algebraic over , and so (V, p. 19, Prop. 3), E is algebraic over .
Bourbaki puts the proof directly after the statement, so what is above is the statement and its proof together.