Assume that g is semi-simple. Let h be a splitting Cartan subalgebra of g, R the root system of (g,h), B a basis of R, R+ the set of positive roots relative to B, and n+=∑α∈R+gα. The principal nilpotent elements belonging to n+ are the elements of n+ having a non-zero component in gα for all α∈B.
Prop. 8 and Lemma 9 prove that such elements are principal nilpotent. We prove the converse. Evidently we can assume that g is simple. Let h0 and gp be as in Prop. 8 and Lemma 9. Let ω be the highest root, and put ω(h0)=2q; we have q=h−1, where h is the Coxeter number of R, cf. Chap. VI, §1, no. 11, Prop. 31. Then g2q=gω,g−2q=g−ω, and g2k=0 for ∣k∣>q. There exists a principal sl2-triplet (x0,h0,y0). By §1, no. 2, Cor. of Prop. 2, (ad x0)2q(g−ω)=gω, so (ad x0)2q=0. Let x be a principal nilpotent element of g belonging to n+. If k is an algebraic closure of k,x⊗1 and x0⊗1 are conjugate under an automorphism of g⊗kk (Prop. 9), so (ad x)2q=0. There exists λ∈R such that (ad x)2qgλ=0. Put x=∑n≥1xn, where xn∈g2n.
Then
(ad x)2qgλ⊂ (ad x1)2qgλ+∑k>4q+λ(h0)gk= (ad x1)2qgλ, since 4q+λ(h0)≥4q−2q=2q. Now (ad x1)2qgλ⊂g4q+λ(h0), where λ=−ω. Thus, (ad x1)2qg−ω=gω. We have ω=∑α∈Bnαα with nα>0 for all α∈ B (Chap. VI, §1, no. 8, Remark). If there exists α0∈B such that x1∈
∑gα, the relation
α∈B,α=α0
ω∈/−ω+α∈B,α=α0∑kα
implies that gω⊂ (ad x1)pg−ω for all p; this is absurd, so the component of x1 in gα is non-zero for all α∈B.
Bourbaki sets the proof directly after the statement, and the corpus does not separate them, so what is above is the statement and its proof together.