Proposition 30
Tag 0AJQ, permanent. Cite it as [Bourbaki, Tag 0AJQ].
Lie Groups and Lie Algebras, chapter III, § 9. Commutators, centralizers and normalizers in a Lie group
(i) Let be a semi-simple real or complex Lie algebra. Then Int is the identity component of Aut .. (ii) Let G be a semi-simple connected real or complex Lie group. The adjoint group of G is the identity component of Aut . Its centre reduces to the identity element. Every derivation of is inner (Chapter I, § 6, Corollary 3 to Proposition 1) and hence , which proves (i). The first assertion of (ii) follows from (i). The second follows from Proposition 29 (iii) and § 6, no. 4, Corollary 4 (ii) to Proposition 10.
Bourbaki puts the proof directly after the statement, so what is above is the statement and its proof together.